How to unlock Black Widow?
Black Widow is one of the few characters who can become invisible which, in turn, allows you to complete puzzles that require this ability. To unlock her you have to go to Sakaar in Chronopolis (near the battle arena) and complete her side mission. Complete the stages, defeat enemies and save the Avengers - the token is now yours.
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Go to the place presented in the map and speak with Black Widow. She asks you to deal with bandits located in various places. Go to the place marked on your minimap and defeat all bandits. You can fight as any of the characters but personally I recommend Ms. Marvel. Shrink her down - your attack speed will allow you to win fast. This is especially important when you are facing enemies with shields or ninjas. However, if you have to fight with armored enemies, switch to a character who can destroy silver and gold armor (e.g. Iron Man).
In the second part of the mission you have to save Black Widow. Symbiote controls her - Black Widow starts attacking you. Ignore the minions and focus on her. After that you have to destroy the Symbiote so it won't overtake another enemy.
The third part is the same as the previous one but this time you have to save Hawkeye. Destroy the Symbiotes and then the minions. This completes the mission and gives you a new character - Black Widow.
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